Dr. Amrendra K. Singh
Department : Chemistry
Research Interests
Inorganic Synthesis and Catalysis
Publications
Srivastava, N.; Singh, A. K. Protic- or anionic-NHCs with classical-NHC in a single [Ru(CNC)(PPh3)2Cl]Cl pincer complex: Direct comparison of structure & electronic properties and heterolytic H2 splitting. Dalton Trans., 2024, 53, 6870-6874. (Communication)
Nath, S.; Yadav, E.; Raghuvanshi, A.; Singh, A. K. Mechanistic Insights and Comparative Analysis of Ru(II)-NNC Pincer Complexes with Anionic-, Protic-, and Classical-NHCs for Transfer Hydrogenation of Ketones. Catal. Sci. Technol., 2023, 13, 7085.
Singh, R. K.; Yadav, D.; Misra, S.; Singh, A. K. Role of Ancillary Ligands in Selectivity Towards Acceptorless Dehydrogenation versus Dehydrogenative Coupling of Alcohols and Amines Catalyzed by Cationic Ruthenium(II)-CNC Pincer Complexes. Dalton Trans., 2023, 58, 15878.
Singh, R. K.; Yadav, D.; Singh, A. K. Cationic Ruthenium(II)-CNC Pincer Complexes as Phosphine-free Catalysts for Nitrile Hydration to Amides in Aqueous Medium. Mol. Catal., 2023, 549, 113523.
Nath, S.; Yadav, E.; Raghuvanshi, A.; Singh, A. K. Ru(II) Complexes with Protic- and Anionic-Naked-NHC Ligands for Cooperative Activation of Small Molecules. Chem. Eur. J., 2023, 29, e202301971. (Author share link)
Shahid, N.; Singh, R. K.; Srivastava, N.; Singh, A. K. Base-Free Synthesis of Benchtop Stable Ru(III)-NHC Complexes from RuCl3·3H2O and Their Use as Precursors for Ru(II)-NHC Complexes. Dalton Trans., 2023, 52, 4176. (Preprint version – free access)